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Cold Floaters, Hot Sinkers Buoyancy Bottles

A small, sealed glass bottle is ballasted until it barely floats in cold water. Because hot water is slightly less dense than cold, the bottle sinks in hot water, sinks fast in rubbing alcohol, and rides high in salt water. It is a cheap, student-made replacement for a commercial demonstration bar and makes the small density changes of water visible.

Written from Bruce's original workshop handout. Bruce's final review of this plan is in progress.

Cold Floaters, Hot Sinkers Buoyancy Bottles
DifficultyBeginner
Build time30-45 minutes (plus a day to let salt water clear)
CostUnder $5 per bottle
SafetyEveryday care
Good forTeachers, Families

What it shows

The same little bottle floats in cold tap water and sinks to the bottom in hot.

Key ideas: density, buoyancy, thermal expansion, Archimedes' principle, kinetic theory

Safety (Everyday care). Empty nail polish bottles outdoors: the fumes are strong and the polish is flammable. Use hot water straight from the tap, not boiling water. Keep rubbing alcohol away from flames. Handle glass bottles and glass cylinders with care.
Construction

Build it

  1. Collect small rigid bottles

    Gather small bottles with screw caps that seal well. Glass works best, hard plastic is next best, and soft squeezable bottles give inconsistent results. Expect about half of all nail polish bottles to be too heavy to float even when empty.

    Step 1
  2. Empty nail polish outdoors

    If you are using nail polish bottles, pour out most of the polish outside. Leave some in; it can serve as the ballast.

    Step 2
  3. Float-test the bottle

    Gently lower the capped bottle into a cup of water. If it sinks, remove very small amounts of the contents until it just barely floats. If it floats too easily, add a little water or a few grains of gravel back in.

    Step 3
  4. Use gravel for fine tuning

    In plastic bottles, aquarium gravel is the easiest ballast: you can adjust a few grains at a time and it does not jam the threads like sand. Always leave an air bubble inside so the contents have room to expand when warmed.

    Step 4
  5. Seal the cap

    Once the bottle barely floats, screw the cap down tightly and run glue around the cap edge. A leak lets air out in hot water and water in when it cools, which ruins the delicate balance.

  6. Recheck the balance

    When the glue is dry, test the bottle again in room-temperature water. It should float with only the cap and neck above the surface.

  7. Set up the cylinders

    Fill graduated cylinders or tall glasses with: cold tap water; hot tap water; rubbing alcohol; cold water on the bottom with hot water carefully poured on top; and saturated salt water made the day before.

    Step 7
  8. Run the demonstration

    Move the same bottle from cylinder to cylinder. It floats in cold water, sinks in hot water, sinks quickly in alcohol, hangs in the middle of the layered cylinder, and floats noticeably higher in salt water.

    Step 8
  9. Let it sit

    Leave the bottle at the bottom of the hot-water cylinder for a while. As the water cools, the bottle rises again.

    Step 9
The physics

How it works

Density is mass per volume. When water is heated its particles move faster and spread slightly farther apart, so the same mass takes up more room and the density drops. Room-temperature water is about 0.998 grams per milliliter; hot tap water is roughly 0.98 to 0.99.

The buoyant force on the bottle equals the weight of the water it pushes aside. The bottle has been tuned so its overall density is just under that of cold water, so it floats. In hot water, each milliliter displaced weighs a little less, the buoyant force falls below the bottle's weight, and it sinks. A rigid glass bottle barely changes size when warmed, which is why glass works best; a soft bottle would swell as its trapped air warms and spoil the effect.

Rubbing alcohol is much less dense than water, so the bottle sinks quickly in it. Saturated salt water is about 1.2 grams per milliliter, so the bottle floats higher in it and still floats even when the salt water is hot.

Water is unusual: it is densest at about 4 degrees C. Below that it expands slightly as it approaches freezing, and ice is less dense than liquid water, which is why ice floats.

Using it

  • Show that several bottles all just barely float in a bucket of cold water, then ask students to predict what each will do in the prepared cylinders.
  • Do not tell students what is in each cylinder; have them infer which liquid is denser from how the bottle behaves.
  • Ask: the bottle sinks faster in alcohol than in hot water. What does that tell you about alcohol?
  • In salt water, look at how high the top of the bottle rides compared to fresh water, and connect it to the buoyant force.
  • Have students build and tune their own bottles, then test their ideas with the materials provided.
Go further

Variations

  • Make a class set of bottles in different colors and use them together.
  • The same idea works with bigger bottles in bigger containers of water.
  • Small glass vials with water or sand as ballast also work, although water ballast can confuse some students about what is happening.
If it doesn't work

Troubleshooting

If this happensThe bottle will not float even when empty.Try thisIt has too much glass for its volume. Try a different bottle; many nail polish bottles are simply too heavy.
If this happensIt floats in both hot and cold water.Try thisIt is floating too high. Add a few grains of gravel or drops of water until it only just floats in cold water.
If this happensResults change from day to day.Try thisThe cap is leaking. Reseal it with glue, and avoid snap-on lids and soft bottles.
If this happensThe salt water is cloudy.Try thisMake it the day before so it has time to clear.

© Bruce Yeany · Homemade Science with Bruce Yeany · youtube.com/@YeanyScience
Free for personal and classroom use. Please don't resell or republish. Build and use at your own risk; follow the safety notes and supervise children.